The gtl plant design has two parallel trains each consisting of a world scale air separation plant, an autothermal reformer, and a slurry phase fischertropsch reactor. The gtl plant design has two parallel trains each consisting of a world scale air separation plant. Standalone autothermal reforming atr is advantageous because it does not require the supply or dissipation of thermal energy to or from the reaction. Pdf the autothermal low temperature catalytic partial oxidation of methane was investigated in a bench scale reactor 1 kw th power over a. Autothermal reforming atr is an important industrial process used to produce syngas with a low h2co ratio from 1. To better understand diesel reforming and the chemistry involved, we have investigated the autothermal reforming of several major diesel constituents in a kilowattscale reactor.
A typical autothermal reforming process scheme, as illustrated in fig. Autothermal reforming atr, one of the alternatives to. Natural gas reforming an overview sciencedirect topics. In reactors some such as the packed bed or fluidized catalytic cracking unit fccu, the momentum balance is considered with both the mass and energy balances. Conventional autothermal reforming process comprises three main reactions. Autothermal reforming of natural gas to synthesis gas reference.
In the atr operation condition where steam is supplied to the reactor in excess, parmar et al. Steam srm and autothermal atr reforming of methane processes were evaluated through thermodynamical and stoichiometric analyses that benefit hydrogen production, using a nigal 2 o 3 catalyst. Diesel reforming poses several unique technical challenges, however. Autothermal reforming an overview sciencedirect topics. Autothermal reforming at low steamtocarbon ratio the majority of the worlds syngasproducing plants apply steam methane reforming, with the specific type of reforming technology depending on application and operating conditions. Optimization of a methane autothermal reformingbased. The purpose is to increase the ratio between steam reforming and partial oxi.
A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Catalytic partial oxidation cpox requires the use of a catalyst, and the fuel. Describes the operation and the equations used to model an autothermal reactor. Today, atr technology replaces twostep reforming technology in topsoes optimized solution for largescale methanol plants 1. Partial oxidation reactions occur in a region of the reactor referred to as the. Microkinetic analysis for model reduction marm dixita, renika baruaha, dhrupad parikha, sudhanshu sharmaa, atul bhargava,1 aenergy systems laboratory, iit gandhinagar, ahmedabad, gujarat, india abstract methane autothermal reforming has been studied using comprehensive, detailed microkinetic. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. Basic objectives in design of a reactor in chemical engineering physical operations such as fluid flow, heat transfer, mass transfer and separation processes play a very large part. Describes how to use an interactive simulation that solves the differential equations for an autothermal reactor, which is a catalytic reactor in which the feed gas is preheated in an annular. The scientific work in the fuel processing and systems group at forschungszentrum juelich has the strategic aim of developing a hightemperature polymer electrolyte fuel cell ht pefc system based on the autothermal reforming of middle distillates such as diesel and. Acknowledgement this work was supported by the national natural science foundation of china no. Autothermal reforming the use of autothermal reformers in syngas manufacture for ammonia and methanol production began in the middle of the last century 3, 4.
The following are the advantages of using the autothermal reforming process. This may be done in a tubular catalytic steam reformer with a furnace to provide external heat, in an autothermal reformer where partial oxidation is combined with adiabatic catalytic steam reforming, or in a partial oxidation reformer followed by a shift reactor. John bogild hansen haldor topsoe methanol workshop, lund university march 17, 2015. A modelling and experimental approach article in international journal of hydrogen energy january 2015 with 173 reads how we measure reads. The concepts use heat available in the process gas downstream an atr for steam reforming in a heat exchanger type of reactor. Autothermal reforming of methane on rhodium catalysts. The standard reactor design for an autothermal fixedbed reactor consists of an adiabatic fixed bed of catalyst which is connected with a heat exchanger so that the hot reactor effluent heats up the cold feed. Autothermal reformer an overview sciencedirect topics. Jc 2001 design of adiabatic fixedbed reactors for the partial oxidation. The main, and most widespread, reactor designs for ngr are steam methane reforming smr and autothermal reforming atr. Developed in the late 50s, atrs main application was for ammonia and methanol syntheses. Pdf modeling an simulation of an autothermal reformer.
Improve syngas production using autothermal reforming. Autothermal reforming atr syngas generation air liquide. Mar 06, 20 describes the operation and the equations used to model an autothermal reactor. Thermal management of methanol reforming reactors for the. Syngas conversion uses hydrocarbon feedstocks, steam, osub 2 and cosub 2, either separately or in combinations. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated.
Design and performance of a kw scale reformer using pure oxygen as oxidant. A reactor design which can maximize the enthalpy in the reforming channels will be highly beneficial to the reforming process and the overall thermal efficiency. Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively. Nov 07, 20 abstract the conceptual design of compact, standalone autothermal reforming systems using methanol is presented. The various reactor designs, fuel delivery systems and catalysts and. The modeling, kinetic analysis, and simulation of atr o f methane for prescribed reactors have been studied 1012.
Autothermal reforming atr is a process for producing syngas, composed of hydrogen and carbon monoxide, by partially oxidizing a hydrocarbon feed with oxygen and steam and subsequent catalytic reforming. Advanced modelling and optimisation of natural gas reforming. In any manufacturing process where there is a chemical change. The reactor performance of two novel fluidized bed membrane reactor. This feature makes atr useful for many applications, and it has been proven industrially to provide quality syngas for largescale plants. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Autothermal reforming of natural gas to synthesis gas. Based on specific conditions of maximum waste heat recovery, the optimization algorithm for maximizing hydrogen yield is obtained. Together with the hightemperature polymer electrolyte fuel cell, the reactor for the autothermal reforming atr of liquid hydrocarbons, such as. When reforming is followed by ft, it is possible to recycle ft tail gas to the. Mann prepared by sandia national laboratories albuquerque, new mexico 87185 and livermore, california 94550 sandia is a multiprogram laboratory operated by sandia corporation. The integration of reaction and heat exchange within one piece of equipment has advantages over the conventional. Effect of catalytic cylinders on autothermal reforming of methane. The combined output from these two trains feeds a single train isocracker.
Dec 23, 2015 autothermal reforming or oxidative steam reforming is a combination of conventional steam reforming of the fuel endothermic reaction with the partial oxidation of a small amount of the fuel exothermic reaction in order to achieve an autothermal reaction that proceeds without external input of energy chang et al. In this autothermal reactor, an exothermic reaction takes place in a packed bed of catalyst a plug flow tubular reactor. A more detailed comparison of the performance of the two proposed reactor concepts is carried out with a simulation study and is presented in the second part of this work. Ab two fluidized bed membrane reactor concepts for hydrogen production via autothermal reforming of methane with integrated co2 capture are proposed. Because co is denatured to h2 of equivalent mol volume in the poststage shift reactor of an autothermal reformer.
Design and control of standalone autothermal reforming. Topsoe offers several types of reforming technologies and has. Steam srm and autothermal atr reforming of methane processes were evaluated through thermodynamical and stoichiometric analyses that benefit hydrogen production, using. These challenges result from the physical and chemical properties of diesel fuel. If we consider the countercurrent heat exchanger of fig. Cameron, in studies in surface science and catalysis, 2001.
A novel reactor type for autothermal reforming of diesel fuel and kerosene. The process is sootfree due to burner design and fixedbed catalyst. Mar 24, 2008 hydrogen production via autothermal reforming atr is particularly attractive for applications that demand a quick startup and response time in a compact size. The feed gas enters an annular region around the packed bed, but flows in the opposite direction from that in the packed bed. Therefore, flow conditions, the heat release, and the risk of soot formation are different in the autothermal and secondary reformers resulting in different requirements to burner and reactor design.
While these two will be described hereinafter, other important reforming technologies include catalytic and noncatalytic partial oxidation and, more recently developed, heat. Autothermal reactor learncheme educational resources for. Reforming of diesel fuel for transportation applications. Reforming technologies to improve the performance of combustion. A novel reactor concept with autothermal operation is presented for the simultaneous production of ethylene by oxidative coupling ocm and synthesis gas by steam reforming of methane srm. This dissertation presents initial developments on ngr modelling in gproms. Autothermal operation of the reactor was successfully demonstrated.
Autothermal fixedbed reactor concepts sciencedirect. Effect of catalytic cylinders on autothermal reforming of. With regard to methane reformingbased hydrogen production processes, a combination of partial oxid ation and steam reforming of methane in an autothermal reform ing atr reactor has recently become more popular. A novel reactor type for autothermal reforming of diesel fuel. Advanced modelling and optimisation of natural gas. Autothermal reactor interactive simulation youtube. This chapter also discusses autothermal reactors, the conversion of ammonia, and finally, the optimumtemperature progression, with derived equations for reversible exothermic reactions. Autothermal reforming of methane with integrated co2 capture.
The autothermal reforming reactor consists of three zones. Tubular reforming and autothermal reforming of natural gas. Autothermal reforming atr is a lowinvestment process using a simple reactor design. Proven autothermal reforming technology for modern large. Advances in autothermal reformer design request pdf.
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